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negative entropy of mixing for vanadium

  • Standard Thermodynamic Values - DrJez

    31 Standard Thermodynamic Values Formula State of Matter Enthalpy (kJ/mol) Entropy (J mol/K) Gibbs Free Energy (kJ/mol) (NH 4) 2O (l) -430.70096 267.52496 -267.10656 (NH 4) 2SiF 6 (s hexagonal) -2681.69296 280.24432 -2365.54992

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  • Olivier Delaire | Duke Mechanical Engineering and …

    2020/04/30· Olivier Delaire Associate Professor of Mechanical Engineering and Materials Science Olivier Delaire's research program investigates atomistic transport processes of energy and charge, and thermodynamics in energy ...

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  • vanadium mixing

    vanadium mixing Email: [email protected] Chemistry of Vanadium Vanadium(V) oxide as a Catalyst. During the Contact Process for manufacturing sulfuric acid, sulfur dioxide has to be converted into sulfur trioxide, which is done ...

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  • CORE

    Negative Entropy of Mixing for Vanadium-Platinum Solutions By O. Delaire, T. Swan-Wood and B. Fultz Download PDF (320 KB) Abstract The phonon densities of states for pure vanadium and the solid solutions V-6.25% Ni, Pd ...

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  • Design of high-strength refractory complex solid …

    2018/03/28· High-entropy alloys based on refractory elements may achieve higher temperature operation with superior creep strength. 3 Typical refractory high-entropy alloys exhibit a yield strength of 500 ...

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  • The structure and properties of high-entropy alloys and …

    A disordered solution whose entropy of mixing fully compensates the influence of both positive and negative enthalpy can form only for particular elemental compositions. 67, 68, 74 Taking into account this fact, the notion 'high

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  • Negative Entropy of Mixing for Vanadium-Platinum …

    Negative Entropy of Mixing for Vanadium-Platinum Solutions Autores: O. Delaire, T. Swan-Wood Localización: Physical review letters, ISSN 0031-9007, Vol. 93, Nº. 18 ...

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  • THERMODYNAMIC PROPERTIES OF THE CR-AL AND V ...

    The entropy of mixing for the solid solution of Al in Cr is positive. A sharp change to a more negative integral entropy of mixing occurs for Cr5Al8, Cr4Al9 and CrAl4 intermetallic compounds, with a value of -1.54 e.u. at 80 at.% Al

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  • Effect of electron count and chemical complexity in the …

    2016/11/15· High-entropy alloys are a new class of materials that consist of several principal elements arranged on simple lattices. These structures are stabilized by the high configurational entropy of the random mixing of the elements. Here, we show that the properties of a superconducting high-entropy alloy are strongly related to the electron …

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  • Stability of rhombohedral phases in vanadium at high ...

    2015/07/13· Stability of rhombohedral phases in vanadium at high-pressure and high-temperature: first-principles investigations Yi X. Wang, 1, 2 Q. Wu, 1 Xiang R. Chen, a, 2 and Hua Y. Geng b, 1 1 National Key Laboratory of Shock Wave and Detonation Physics, Institute of Fluid Physics, CAEP, P.O. Box 919-102, Mianyang 621900, …

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  • The Phonon Entropy of Transition Metals and Alloys: …

    Alloying with 6% Pt solutes produces a strong stiffening of the phonon DOS, inducing a large and negative vibrational entropy of mixing, which overcomes the increase in configurational entropy. A systematic study of chemical

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  • MoNbTaV Medium-Entropy Alloy - MDPI

    entropy Article MoNbTaV Medium-Entropy Alloy Hongwei Yao 1, Jun-Wei Qiao 1,*, Michael C. Gao 2,3,*, Jeffrey A. Hawk 2, Sheng-Guo Ma 4 and Hefeng Zhou 1 1 Laboratory of Applied Physics and Mechanics of Advanced Materials, College of …

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  • CORE

    Negative entropy of mixing for vanadium-platinum solutions, (1989). Neutron multiple scattering and absorption

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  • Entropy of activation | Article about entropy of activation …

    The corrosion parameters such as activation energy ([E.sub.a]), enthalpy of activation ([DELTA]H*), and entropy of activation ([DELTA]S*) for mild steel in 1 mol [L.sup.-1] HCl solution in the absence and presence of GAI with different concentrations (10-60 ppm) at various immersion periods in the temperature range of 303-323 K were calculated and …

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  • Olivier Delaire | [email protected]

    Olivier Delaire's research program investigates atomistic transport processes of energy and charge, and thermodynamics in energy materials (DOE Early Career Award 2014). His research group studies elementary excitations in ...

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  • Negative Entropy of Mixing for Vanadium-Platinum …

    Negative Entropy of Mixing for Vanadium-Platinum Solutions O. Delaire, T. Swan–Wood, and B. Fultz California Institute of Technology, W. M. Keck Laboratory, mail 138-78, Pasadena, California 91125, USA (Received 9 April 2004

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  • Negative Entropy of Mixing for Vanadium-Platinum …

    Negative Entropy of Mixing for Vanadium-Platinum Solutions Delaire, O. and Swan-Wood, T. and Fultz, B. (2004) Negative Entropy of Mixing for Vanadium-Platinum Solutions. Physical Review Letters, 93 (18).

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  • Hybrid Monte Carlo/Molecular Dynamics …

    Hybrid Monte Carlo/Molecular Dynamics Simulation of a Refractory Metal High Entropy Alloy MICHAEL WIDOM, W.P. HUHN, S. MAITI, and W. STEURER The high entropy alloy containing refractory metals Mo-Nb-Ta-W has a body

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  • Fultz Group Older Abstracts - California Institute of …

    The vibrational entropies of mixing 6.25% substitutional solutes into vanadium were, for Ni, Pd and Pt solutes, -0.082, -0.185 and -0.272 k_B/atom, respectively. For V-6.25% Pt, the negative vibrational entropy of mixing exceeds

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  • The phonon entropy of transition metals and alloys: Effects …

    For a fixed configuration of ions on a given crystalline lattice, low energy excitations around the static average configuration can be thermally activated and will contribute to the entropy of the system. As such, phonons, spin-waves or electronic excitations have their own entropic contribution. This thesis investigates the entropic effects of lattice …

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  • Entropy | Free Full-Text | MoNbTaV Medium-Entropy Alloy ...

    The present study focuses on a medium-entropy alloy MoNbTaV with the objective of achieving a single BCC structure with lower density and higher ductility than MoNbTaW. Vanadium has a significantly lower density (6.11 g/cm 3) than tungsten (19.25 g/cm 3), while the former has a much higher Poisson's ratio (0.365) than the latter (0.28) [7,25].

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  • Negative entropy of mixing for vanadium-platinum …

    Title Negative entropy of mixing for vanadium-platinum solutions. Publication Type Journal Article Year of Publication 2004 Authors O Delaire, T Swan-Wood, and B Fultz Journal Physical Review Letters Volume 93 Issue 18 Start Page

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  • Design of high-strength refractory complex solid-solution alloys

    2018/03/28· @article{osti_1433653, title = {Design of high-strength refractory complex solid-solution alloys}, author = {Singh, Prashant and Sharma, Aayush and Smirnov, A. V. and Diallo, Mouhamad S. and Ray, Pratik K. and Balasubramanian, Ganesh and Johnson, Duane D.}, abstractNote = {Nickel-based superalloys and near-equiatomic high-entropy …

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  • Phonon Entropy of Alloying in Dilute Vanadium Alloys

    We show that for Ni, Pd and Pt impurities, the phonon entropy of alloying is large and negative, and in the case of Pt it results in a negative total entropy of mixing for 6% impurities. A Born-von Karman model was used to invert the

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  • Guidelines in predicting phase formation of high-entropy …

    2014/04/23· If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your account. Find out more about sending content to Dropbox . Guidelines in predicting phase formation of high-entropy alloys

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  • Thermodynamic properties in the systems vanadium …

    2019/03/23· Vanadium Hydride as Conversion Type Negative Electrode for All-Solid-State Lithium-Ion-Battery. MATERIALS TRANSACTIONS 2019, 60 (10), 2183-2187. DOI: 10.2320/matertrans.MT-M2019105.

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  • More than entropy in high-entropy alloys Forming solid ...

    2016/01/06· Effect of vanadium addition on the microstructure, hardness, and wear resistance of Al0.5CoCrCuFeNi high-entropy alloy. Metallurgical and Materials Transactions A 2006;37A:1363e9. [47] Yang JY, Zhou YJ, Zhang Y, Chen GL

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  • Tabitha SWAN-WOOD | California State University, …

    2020/02/15· Tabitha SWAN-WOOD of California State University, Channel Islands, California (CSUCI) | Read 17 publications | Contact Tabitha SWAN-WOOD

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  • Negative Entropy of Mixing for Vanadium-Platinum …

    2004/10/01· The phonon densities of states for pure vanadium and the solid solutions V-6.25% Ni, Pd, Pt were determined from inelastic neutron scattering measurements. The solute atoms caused a large stiffening of the phonons, resulting in large, negative vibrational entropies of mixing. For V-6.25%Pt, the negative vibrational entropy of mixing exceeds the conventional positive chemical entropy of mixing ...

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  • Negative Entropy of Mixing for Vanadium-Platinum …

    Negative Entropy of Mixing for Vanadium-Platinum Solutions

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